is an apparatus for rapid quantitative and qualitative
analysis of hydrocarbon compounds in a petroleum sample. It utilizes the
principle of accelerating molecules in a circular path in an electrical
field. The compounds are separated by centrifugal force, with the molecules
having a greater mass (weight) being thrown to the outer periphery of the
path. Quantitative measurements are accomplished by use of either a
photographic plate or electronic determination of the relative proportions
of each type of particle of a given mass.
All mass spectrometers consist of three basic parts: an ion source,
a mass analyzer, and a detector system. The stages within the
mass spectrometer are:
- Producing ions from the sample
- Separating ions of differing masses
- Detecting the number of ions of each mass produced
- Collating the data and generating the mass spectrum
The technique has several applications, including:
- identifying unknown compounds by the mass of the compound molecules or
their fragments
- determining the "isotopic" composition of elements in a compound
- determining the "structure" of a compound by observing its
fragmentation
- quantifying the amount of a compound in a sample using carefully
designed methods (mass spectrometry is not inherently quantitative)
- studying the fundamentals of "gas phase ion chemistry" (the chemistry
of ions and neutrals in vacuum)
- determining other physical, chemical, or even biological properties of
compounds with a variety of other approaches
Also see chromatography,
clay/silica gel analysis,
ferrography,
infrared analysis, particle count,
spectrographic analysis.